☞ To add a new item to the existing dictionary, extend it with a single pair of values.
Syntax :<dictionary_name> [<key>] = value
D = {10:"Ten", 20:"Twenty"}
print(D)
D[30] = "Thirty"
print(D)
{10: 'Ten', 20: 'Twenty'}
{10: 'Ten', 20: 'Twenty', 30: 'Thirty'}